煤炭工程 ›› 2016, Vol. 48 ›› Issue (2): 91-94.doi: 10.11799/ce201602028

• 研究探讨 • 上一篇    下一篇

充填开采复合胶结材料理化与力学性能试验研究

张镇   

  1. 天地科技股份有限公司开采设计事业部
  • 收稿日期:2014-12-12 修回日期:2015-04-01 出版日期:2016-02-10 发布日期:2016-03-07
  • 通讯作者: 张镇 E-mail:ccrizhen@126.com

Experimental study on physico-chemical and mechanical properties of composite cementing material for backfill mining

  • Received:2014-12-12 Revised:2015-04-01 Online:2016-02-10 Published:2016-03-07

摘要: 根据水泥复合化原理,采用试验配比的方法,选取常用的复合硅酸盐水泥、硫铝酸盐水泥和二水石膏进行配比试验,研究复合胶结材料的水化机理、水化产物特征和主要指标性能,得到复合胶结材料的最优配比。研究结果表明,复合胶结材料水化早期生成钙矾石,起到早强快凝作用,中期及后期产物以水化硅酸钙凝胶和氢氧化钙凝胶为主,且与钙矾石交织成致密结构,增加材料抗压性能;复合胶结材料的标准稠度用水量随硫铝酸盐水泥和石膏掺量的增加而增加,凝结时间随硫铝酸盐水泥掺量的增加而缩短,其抗压强度均高于基础组分复合硅酸盐水泥的强度;复合胶结材料最优配比为硫铝酸盐水泥掺量不宜超过15%,二水石膏掺量不宜超过10%。采用复合胶结材料制成的膏体材料各项指标满足工程的需要。

关键词: 充填开采, 复合胶结材料, 力学性能, 水化产物

Abstract: According to the cement compositing principle, the composite Portland cement, CSA cement and dihydrate gypsum were selected to be proportioning tested, in order to research the hydration mechanism, hydration products characteristics and main index of performance, eventually the optimal proportion of composite cementing material was got. Experimental results show that the main early hydration product was AFt, which made the cement set rapidly and results in the high early mechanical strength. The main mid and last hydration products were CSH gel and CH gel, which were interlaced with AFt and increased the compressive strength of material. Water requirement of normal consistency was increased with the addition of CSA cement and dihydrate gypsum. The setting time was shortened with CSA cement and dihydrate gypsum increases. The compressive strength were higher than the base composite Portland cement. The optimal proportion of composite cementing material is that CSA cement dosage should not be more than 15% and the dihydrate gypsum dosage should not exceed 10%. The indicates of paste filling material made by the composite cementing material meet the engineering needs.

中图分类号: